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Magnetic, electrical and thermodynamic properties of RE8Pd24In

Identifieur interne : 003D43 ( Main/Repository ); précédent : 003D42; suivant : 003D44

Magnetic, electrical and thermodynamic properties of RE8Pd24In

Auteurs : RBID : Pascal:11-0006829

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Abstract

Investigations of magnetic, transport and thermodynamic properties of RE8Pd24In (RE = Pr, Nd, Gd, Tb, Dy, Ho, Er and Tm) are reported through measurements of X-ray diffraction, electrical resistivity (ρ(T)), magnetic susceptibility (χ(T)), magnetization (σ(μ0H)) and heat capacity (Cp(T)). These ternary compounds have the cubic AuCu3-type structure. Compounds with RE = Gd and Tb order antiferromagnetically (AF) and exhibit magnetic transitions observed in their χ (T) and Cp(T). ρ(T) results for the Gd and Tb compounds indicate a minimum above the magnetic phase transition temperature TN, and an increase in ρ(T) upon further cooling as a precursor ofAF order at lower temperatures. χ (T) data at high temperatures follow the Curie-Weiss relation for all compounds and give effective moment values close to those expected for the free RE3+-ion. Enhanced values of the electronic contribution to the heat capacity were observed for Gd8Pd24In and Tb8Pd24In.

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<sub>24</sub>
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<div type="abstract" xml:lang="en">Investigations of magnetic, transport and thermodynamic properties of RE
<sub>8</sub>
Pd
<sub>24</sub>
In (RE = Pr, Nd, Gd, Tb, Dy, Ho, Er and Tm) are reported through measurements of X-ray diffraction, electrical resistivity (ρ(T)), magnetic susceptibility (χ(T)), magnetization (σ(μ
<sub>0</sub>
H)) and heat capacity (C
<sub>p</sub>
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<sub>p</sub>
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<sub>N</sub>
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<sup>3+</sup>
-ion. Enhanced values of the electronic contribution to the heat capacity were observed for Gd
<sub>8</sub>
Pd
<sub>24</sub>
In and Tb
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Pd
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<s0>Investigations of magnetic, transport and thermodynamic properties of RE
<sub>8</sub>
Pd
<sub>24</sub>
In (RE = Pr, Nd, Gd, Tb, Dy, Ho, Er and Tm) are reported through measurements of X-ray diffraction, electrical resistivity (ρ(T)), magnetic susceptibility (χ(T)), magnetization (σ(μ
<sub>0</sub>
H)) and heat capacity (C
<sub>p</sub>
(T)). These ternary compounds have the cubic AuCu
<sub>3</sub>
-type structure. Compounds with RE = Gd and Tb order antiferromagnetically (AF) and exhibit magnetic transitions observed in their χ (T) and C
<sub>p</sub>
(T). ρ(T) results for the Gd and Tb compounds indicate a minimum above the magnetic phase transition temperature T
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, and an increase in ρ(T) upon further cooling as a precursor ofAF order at lower temperatures. χ (T) data at high temperatures follow the Curie-Weiss relation for all compounds and give effective moment values close to those expected for the free RE
<sup>3+</sup>
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